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Character:
Iron Man (Tony Stark)
Tony Stark is a cool exec with a heart of steel who fights and smites with repulsor rays.
TALES OF SUSPENSE #61-62 (1965)
TALES OF SUSPENSE #63 (1965): Iron Man/Captain America
TALES OF SUSPENSE #64-65 (1965): Captain America
TALES OF SUSPENSE #64-65 (1965): Iron Man stories; Black Widow Returns
TALES OF SUSPENSE #66-68 (1965): The first Silver Age appearance of the REAL Red Skull
Tales Of Suspense #69-71 (1965): 1st Titanium Man
Tales Of Suspense #72 (1965)
X-Men #9 (1965): vs The Avengers!
AMAZING SPIDER-MAN #18-19 (1964)
AVENGERS #10-11 (1964) 1st Avengers Assemble, Immortus
AVENGERS #3 (1964)
AVENGERS #4 (1964): 1st Captain America
AVENGERS #5 (1964)
AVENGERS #6 (1964): 1st Modern Zemo
AVENGERS #7 (1964): 1st Rick Jones as Bucky
AVENGERS #8 (1964): 1st Kang!
AVENGERS #9 (1964): 1st Wonder Man (dies)
FANTASTIC FOUR #25-26 (1964) and The Top 10 Hulk vs Thing Fights
JOURNEY INTO MYSTERY #101-102 (1964)
JOURNEY INTO MYSTERY #105-106 (1964)
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1960s
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Non-Marvel