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Character:
Black Widow (Natasha Romanoff)
Spy. Sleeps with Hawkeye and Daredevil. But not at the same time.
Yet.
DAREDEVIL #116-117 (1974-1975)
Daredevil #120-123 (1975)
DAREDEVIL #124-125 (1975)
Marvel Two-In-One #10 (1975): Black Widow
THE CHAMPIONS #1-3 (1975-1976)
DAREDEVIL #108-109 (1974)
DAREDEVIL #113-115 (1974)
MAN-THING #1 (1974): Top 20 Gerber comic
MARVEL TWO-IN-ONE #3/DAREDEVIL #110-112 (1974): 1st Silver Samurai
AVENGERS #109, DAREDEVIL #99 (1973)
AVENGERS #110-111 (1973): AvX; Black Widow joins
AVENGERS #112 (1973): 1st Mantis
DAREDEVIL and BLACK WIDOW #102 (1973)
DAREDEVIL AND BLACK WIDOW #103-107 (1973-1974)
DAREDEVIL AND THE BLACK WIDOW #97-98 (1973)
DAREDEVIL #82-83 (1971-1972)
DAREDEVIL #84-85 (1972)
DAREDEVIL #86 (1972)
DAREDEVIL #87-96 (1972-1973)
AMAZING ADVENTURES #5-8 (1971)
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1960s
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Non-Marvel